Some investors view high dividend yields in a negative light. They think any stock with an especially high yield is one to avoid.

Others, though, embrace such stocks. There are even investing strategies focused on buying blue-chip stocks in the Dow Jones Industrial Average with the highest yields. The idea is that these stocks tend to be more attractively valued.

Should you buy the three highest-paying dividend stocks in the Dow Jones right now? Here they are -- and whether or not they're good picks.

1. Walgreens Boots Alliance

Walgreens Boots Alliance (WBA 1.06%) easily ranks at the top of our list. The retail and wholesale pharmacy giant's dividend yield currently stands at nearly 8.4%. Walgreens' yield is sky-high in large part because of its dismal stock performance. The company's share price has plunged close to 40% in 2023 and fell sharply in 2022 as well.

NASDAQ: WBA

Walgreens Boots Alliance
Today's Change
(1.06%) $0.12
Current Price
$10.98
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WBA

Key Data Points

Market Cap
$10B
Day's Range
$10.89 - $11.02
52wk Range
$8.08 - $18.83
Volume
10,778,178
Avg Vol
21,851,314
Gross Margin
15.77%
Dividend Yield
6.82%

Income investors have liked Walgreens for a long time thanks to the company's 47-year track record of dividend increases. However, it appears that streak is about to end. Walgreens hasn't announced a dividend increase this year, and time is quickly running out.

One other side effect of Walgreens' steep stock decline is that it has a bottom-of-the-barrel valuation. Shares trade at a forward price-to-earnings multiple of under 7x.

So is Walgreens stock a good choice to buy right now? I think that it depends on your investing style. The company faces continued business challenges and turnover in its executive team. I expect the stock to remain highly volatile. Risk-averse investors are probably best staying away.

On the other hand, highly aggressive investors seeking a potential long-term turnaround opportunity might like Walgreens. Keep in mind that the company may be forced to cut its dividend at some point, though.

2. Verizon Communications

Verizon Communications (VZ 0.73%) comes in second place among Dow stocks with its dividend yield of nearly 6.9%. In addition to this high yield, the company claims the best track record in the telecommunications industry with 17 consecutive years of dividend increases.

NYSE: VZ

Verizon Communications
Today's Change
(0.73%) $0.32
Current Price
$43.24
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VZ

Key Data Points

Market Cap
$182B
Day's Range
$41.58 - $43.67
52wk Range
$37.59 - $47.35
Volume
37,633,171
Avg Vol
26,246,749
Gross Margin
46.59%
Dividend Yield
6.25%

Investors didn't have much to cheer about with Verizon throughout much of 2023. By early in the third quarter, the stock was down more than 20% year to date. However, Verizon has made an impressive comeback and just might finish the year in positive territory.

This strong rebound is due to the company's better-than-expected third-quarter results. Most importantly, Verizon generated solid free cash flow and even raised its free cash flow guidance for full-year 2023 by $1 billion.

Verizon's dividend appears to be safe and likely to continue growing. The company operates in a highly competitive industry but is taking smart steps to attract new customers and retain existing ones. I think this Dow stock is a good pick for income investors.

3. 3M

The No. 3 highest-paying dividend stock in the Dow is 3M (MMM 8.33%). The large manufacturer's dividend yield tops 5.8%. 3M is also a Dividend King with 65 consecutive years of dividend increases.

I'm not confident that the company will keep its streak of dividend hikes going, though. 3M agreed to pay $6 billion to settle litigation over allegedly faulty military-grade earplugs that it made. This hefty settlement could make it difficult for 3M to pay out its dividend at current levels.

Today's Change
(8.33%) $10.50
Current Price
$136.59
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MMM

Key Data Points

Market Cap
$74B
Day's Range
$130.50 - $137.27
52wk Range
$90.65 - $156.35
Volume
7,943,805
Avg Vol
4,355,284
Gross Margin
42.25%
Dividend Yield
2.08%

Like Verizon, 3M has mounted a comeback after its stock sank during the first three quarters of 2023. The company's Q3 update provided a much-needed catalyst, with increased full-year earnings and cash flow guidance especially helping.

I don't think that 3M is out of the woods just yet, though. My view is that most investors will be better off staying on the sidelines with the stock.